Agricultura
Agricultura
Regulating Electron Transfer in Vanadium‐Based Metal–Organic Frameworks via the Synergy of Linker Engineering and Machine Learning for Efficient and Reversible Aqueous Zinc Ion Batteries
11/06/2025 -
This study proposes a ligand‐engineering strategy to construct a series of functionalized X‐MIL(V)‐47 framework materials, enabling a systematic elucidation of the synergistic mechanisms...
One‐Pot Single‐Step Approach for the Controlled Synthesis of Multifunctional Microparticles
05/06/2025 -
A versatile one‐pot strategy combines bipolar electrochemistry and the water‐organic interface to synthesize in a single‐step complex patchy particles, which cannot be achieved by any other...
Multi‐Generational Frontal Curing and Chemical Recycling of Polydicyclopentadiene Thermosets
16/05/2025 -
Frontal polymerization meets chemical recycling: repeated rapid frontal curing, deconstruction, and chemical regeneration of polydicyclopentadiene thermosets are enabled by a small amount of a...
Mesoporous Silica Microspheres by Super‐Fast Alkaline Etching of Micrometer‐Sized Stöber Particles
13/05/2025 -
Microscale silica particles are prepared along with a modified, scalable Stöber synthesis using the continuous addition of tetraethoxy silane to an ethanolic solution of ammonia with KCl. Etching...
Solution‐Processable PEDOT for Organic Solar Cells: From One‐Pot Synthesis to Kinetically‐Controlled Polymerization
21/04/2025 -
It is shown that the synthesis of solution‐processable poly(3,4‐ethylenedioxythiophene) (PEDOT) hole transporting materials (HTMs) follows the principle of oxidative polymerization‐induced...
Improved Foaming Performance of Thermoplastic Polyether Amide Elastomers via Chain Extension: Toward Self‐Powered Intelligent Footwear
12/03/2025 -
Polyamide 6‐based thermoplastic elastomers (TPAE) with superior tensile strength and elongation‐at‐break are successfully synthesized by one‐pot melt polycondensation. Two different types of...
One‐Pot Hetero‐Di‐C‐Glycosylation of the Natural Polyphenol Phloretin by a Single C‐Glycosyltransferase With Broad Sugar Substrate Specificity
07/02/2025 -
Here, an efficient system for synthesizing high‐value polyphenol hetero‐di‐C‐glycosides with two distinct C‐glycosyl residues was established using a two‐step glycosylation catalyzed by...
Designing Supported Nanoparticles via Synergistic Ex‐Solution and Phosphorization for Tailored Active Site Generation
31/01/2025 -
A one‐pot process synchronizing nanoparticle ex‐solution and phosphorization is developed for simultaneous phosphide nanoparticle synthesis and host oxide functionalization. The resulting...
Transforming Plastics to Single Atom Catalysts for Peroxymonosulfate Activation: Axial Chloride Coordination Intensified Electron Transfer Pathway
05/01/2025 -
A graphene‐based single‐atom catalyst with atomically dispersed FeN4Cl sites (Fe─N/Cl─C) is produced from high‐density polyethylene and applied in peroxymonosulfate (PMS) activation and...
Functional and Genomic Potential of Burkholderia contaminans PB_AQ24 Isolate for Boosting the Growth of Bamboo Seedlings in Heavy Metal Contaminated Soils
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Abstract The present study investigated the genomic and functional potential of Burkholderia contaminans PB_AQ24, a bacterial strain isolated from the municipal solid...
Green Synthesis of Urethane‐Linked Tamarind Seed Xyloglucan: Thermal Stability, Antibacterial Properties, and DFT Study
20/12/2024 -
The study presents a one‐pot, solvent‐free synthesis approach for urethane‐linked tamarind seed xyloglucan. The XG‐urethane composite (U‐XG) exhibits enhanced thermal stability and superior...
Polymorphing Hydrogels Regulated by Photo‐reactive DNA Cross‐links
01/12/2024 -
Photo‐reactive DNA‐cross‐linked hydrogels are presented that enable polymorphing under patterned light. The photo‐reactive DNA crosslinks act as a regulator in morphing of the hydrogels,...
Enantioselective Cascade Reactions of Aminocatalytic Dienamines and Trienamines Initiated by a Cycloaddition Reaction
19/11/2024 -
This review outlines and showcases how aminocatalytic dienamines and trienamines can be used in stereoselective cascade reactions, that are initiated by a cycloaddition reaction to rapidly access...
Site?Selective ??Trihalomethylation and ??Dihalomethylidenation of Silyl Dienol Ethers under Organophotoredox Catalysis
19/11/2024 -
We report a general remote tribromo? and trichloromethylation process using CBr4 and CBrCl3 as ready available sources of trihalomethyl radicals. This method operates under mild and metal?free...
A Cascade Synthesis of Furo?Pyrrolo?Pyridines via Pd(II)?Catalyzed Dual N?H/C Annulative?Cyclization
18/11/2024 -
A Pd(II)?catalyzed non?template synthesis of furo[2,3?b]pyrrolo[2,3?d]pyridines from b?ketodinitriles and buta?1,3?diynes has been accomplished via dual annulative cyclization. The participation of...
Synthesis, Characterization, and Thin?Film Properties of Post?Functionalized N,N?Dimethylanilinoethynyl?Substituted Cyclobutenofullerenes
18/11/2024 -
A ??extended cyclobutenofullerene containing an N,N?dimethylanilinoethynyl group was synthesized via a one?pot cascade reaction of C60 with the corresponding propargylic phosphate. The...
Substrate?Dependent Stereoselective Synthesis of Pyrrolo[3,4?b]pyridin?5?ones and Pyridyl?isoindoline?1?ones using Bis(benzotriazol?1?yl) Ligand
18/11/2024 -
The documented work highlighted the synthesis of bis(benzotriazol?1?yl) methane derivatives using silicomolybdic acid (SMA) and successfully implemented in the stereoselective synthesis of diverse...
Site?Selective Direct ??Difunctionalization of Diazoenals: Application to the Synthesis of Enal?Functionalized Allenes and Furans
19/11/2024 -
??Difunctionalization of diazoenals: Rh?catalyzed reaction of diazoenals and propargyl sulfides provided a direct access to the ??difunctionalized allenyl(sulfanyl)enals having a quaternary...
Foliar Biofortification of Maize (Zea mays L.) with Selenium: Effects of Compound Type, Application Rate, and Growth Stage
21/11/2024 -
Nowadays, attention is focused on the lack of selenium in the average diet, which is a highly valued element in the body’s antioxidant system. The major metabolites of selenium are...
Comprehensive Investigation of Epoxy Adhesives for Structural Applications in Saudi Arabia: Mechanical Performance, Environmental Impacts, and Analysis on Health
16/11/2024 -
Epoxy adhesives possess excellent mechanical properties, durability, and stability in harsh environments, making them suitable for producing engineering materials. This study selects four...
Ternary Ni?Sb?Te Nanoparticles by Co?Reduction in a One?Pot Microwave?Assisted Polyol Process
13/11/2024 -
A rare case. Nanoparticles of ternary Ni?Sb?Te compounds were prepared in a simple one?pot microwave?assisted polyol process without additional reducing reagents. The compounds generally adopt...
