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Aromatic‐to‐Antiaromatic Switching in Triply Linked Porphyrin Bis(rhodium(I)) Hexaphyrin Hybrids (pages 889–893)

Switch 'em up: Two‐electron oxidation and reduction switches the title complexes between aromatic and antiaromatic character (see picture). The switching is confirmed by 1H NMR and UV/Vis/NIR absorption spectroscopy and by cyclic voltammetry. The structure of the porphyrin–[26]hexaphyrin hybrid tape was elucidated by X‐ray diffraction analysis.

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Fuente: CHEMISTRY - AN ASIAN JOURNAL

Tecnologías:
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Autor: Takayuki Tanaka1, Dr. Naoki Aratani1,2, Prof. Dr. Atsuhiro Osuka1,*

Referencia: Chemistry – An Asian JournalVolume 7, Issue 5, pages 889–893, May 2012

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